COMPOSITIONAL VARIATIONS IN A FERTILE MANTLE DOMAIN: PERIDOTITE XENOLITHS FROM THE TARIAT REGION, MONGOLIA
D. Ionov, GEMOC Macquarie
Introduction
Continental lithospheric mantle is heterogeneous in terms of modal
and chemical composition. There are fundamental differences between
cratonic and younger mantle (Boyd et al., 1997), and non-cratonic
mantle has broad compositional variations worldwide (McDonough,
1990). Xenoliths of spinel peridotites in alkali basalts are direct
samples of lithospheric mantle but it may not be clear whether
a single xenolith suite can provide a representative sample of
the mantle in a given lithospheric unit. The range and scale of
compositional variations in a mantle volume can be established
by representative sampling of xenoliths from different eruption
centres of a similar age. Questions of particular interest are
(i) whether lithospheric mantle in individual tectonic units has
limited variation ranges specific to each unit, (ii) the scale
of mantle heterogeneity and spatial relationships between rock
types, and (iii) the relationship between variations in modal
composition (including accessory minerals), major and trace element
compositions.
Samples and methods
These questions are addressed here using petrologic and geochemical data for several xenolith suites from the Plio-/Pleistocene Tariat basaltic field in central Mongolia. Press et al. (1986) and Stosch et al. (1986) provided petrologic, trace element and Sr-Nd isotope data for 12 spinel peridotite xenoliths from the Shavaryn-Tsaram site in the Tariat region. They found that the xenolith suite is dominated by 'primitive' to slightly depleted lherzolites and argued for an unusually primitive upper mantle beneath Mongolia. However their study based on a limited number of samples from a single eruption centre did not demonstrate whether these compositions are unique for that site or characterise a large mantle domain.
This work is based on a study of more than 70 spinel peridotite
xenoliths from four other eruption centres in the Tariat region
(Haer, Shute, Tsagan and Zala) located within 20 km of each other.
All these samples were studied petrographically and their minerals
analysed for major elements by electron microprobe (EMP). Whole
rock major element compositions were determined for 30 xenoliths
by XRF; trace element composition of clinopyroxene (cpx) in 32
xenoliths were obtained by laser ablation ICP-MS. These results
are compared with published and new original data for xenoliths
from Shavaryn-Tsaram.
Results
Relative position of the xenoliths in the lithospheric cross-section was estimated by projecting a temperature estimate for each xenolith on the local geotherm constructed earlier based on garnet-bearing xenolihts from Shavaryn-Tsaram (Ionov et al., 1998). At two sites, Shavaryn-Tsaram and Zala, the xenoliths show the largest range of T values from ~880 to 1100°C and appear to provide continuous sampling of the spinel lherzolite facies mantle from the crust-mantle boundary to the deeper garnet lherzolite facies. At three other sites the T values do not exceed ~1000°C and correspond to the uppermost mantle only.
The xenoliths at the four new sampling sites range from fertile to moderately depleted spinel lherzolites with cpx contents between 8 and 20 wt.%. No harzburgites were found. The lherzolites from all these sites show a similar range of bulk composition, with Al2O3 varying from 2 to 4.7 wt % and a more limited range of 3-4 wt.% Al2O3 in the majority of the samples. The average whole-rock compositions at each site are also similar, with 3.4-3.8 wt.% Al2O3 and 3.0-3.2 wt.% CaO; the average composition of the xenoliths from Shavaryn-Tsaram reported by Press et al. (1986) also falls within these ranges. Rare harzburgites and cpx-poor lherzolites have been found at Shavaryn-Tsaram where mantle xenoliths are particularly abundant, but these rock types are very subordinate. Overall, the compositional ranges and average compositions are similar for all the xenolith occurences in Tariat.
The majority of the Tariat lherzolites are coarse- to medium-grained rocks with protogranular microstructure. The xenolith suites at each site have similar textures but can be distinguished by the occurrence and relative abundance of accessory amphibole and mica, fine-grained interstitial material and fluid inclusions in minerals. Amphibole occurs only in the Tsagan xenolith suite in which it is fairly common (found in 8 samples out of 15). Phlogopite occurs in xenoliths from three sites: it is very common in xenoliths from Shute (eight out of 12) but rare in xenoliths from Haer (three out of 20) and Tsagan (two out of 15). Amphibole and mica have not been found in 25 xenoliths from Zala studied; in three Zala xenoliths more than half the clinopyroxene is replaced by spongy aggregates. Many xenoliths from Haer have abundant fluid inclusions in pyroxenes.
Clinopyroxene is depleted in light REE relative to heavy and intermediate
REE in 28 xenoliths out of 32 analysed for trace elements. In
the majority of the samples clinopyroxenes also have low contents
of highly incompatible trace elements (Nb, Th, U). Interestingly,
five of the REE-depleted xenoliths contain accessory phlogopite
or amphibole, i.e. are modally metasomatised. Clinopyroxene coexisting
with phlogopite is enrihed in LREE only in two xenoliths in which
phlogopite is abundant and texturally equilibrated with tabular-equigranular
lherzolite. Overall, the majority of the Tariat xenoliths show
no geochemical evidence for significant metasomatic enrichment
including some modally metasomatised samples in which the enrichment
was moderate and hosted by interstitial material.
Conclusions
The Tariat peridotites from five eruption centres are charaterised by low to moderate depletion in basaltic components combined with depletion in incompatible trace elements. These results are in general agreement with earlier conclusions of Press et al. (1986) and Stosch et al. (1986) that the Tariat peridotites are more fertile than the average spinel peridotite xenolith suites worldwide. The generally fertile mantle compositions in central Mongolia broadly match those observed in xenoliths from the Baikal region in the north and suggest that the lithospheric mantle in those areas defines a large-scale fertile domain.
The mantle in the Tariat region is relatively homogeneous in terms
of the contents of rock-forming minerals, major element compositions
and trace element patterns in clinopyroxenes reflecting an origin
in a mantle domain that has experienced only low to moderate degrees
of partial melting and melt extraction and was not significantly
metasomatised afterwards. Mantle heterogeneity on a kilometre
scale may be expressed by the presence and different abundances
of specific accessory minerals, interstitial material or fluid
inclusions in minerals. These probably reflect small-scale metasomatic
events induced by upward percolation of small amounts of fluids
with different composition.
References
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Ionov, D.A., O'Reilly, S.Y., and Ashchepkov, I.V. (1995) Contrib. Mineral. Petrol. 122, 174-190.
Ionov, D.A., O'Reilly, S.Y., and Griffin, W.L. (1998) In: Flower M. et al. (eds.) Mantle Dynamics and Plate Interactions in East Asia, AGU Geodynamics Series 27 (in press).
McDonough, W.F. (1990) Earth Planet. Sci. Lett. 101, 1-18.
Press, S., Witt, G., Seck, H.A., Ionov, D.A., and Kovalenko, V.I. (1986) Geochim. Cosmochim. Acta 50, 2587-2599.
Stosch, H.-G., Lugmair, G.W., and Kovalenko, V.I. (1986) Geochim.
Cosmochim. Acta 50, 2601-2614.
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